The kinetics of the oxidation of cyclopentanone with decaneperoxysulfonic acid |
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Authors: | R L Safiullin A N Volgarev V D Komissarov |
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Institution: | (1) Institute of Organic Chemistry, Ural Branch of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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Abstract: | The kinetics of the oxidation of cyclopentanone with decaneperoxysulfonic acid at 291–323 K in CCl4 has been studied. The reaction is not autocatalytic, and its rate increases linearly with increases in the concentrations
of each of the reagents. The addition of CF3COOH does not affect the reaction rate. The observed results are explained within a scheme which is a special case of the
well-known Baeyer-Villiger reaction mechanism established for peroxycarboxylic acids. The effective rate constant of the process
has been determined: logk (L mol−1 s−1)=(7.6±1.7) — (42.1±9.6)/θ, where θ=2.30RT kJ mol−1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1827–1829, October, 1993. |
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Keywords: | oxidation kinetics cyclopentanone decaneperoxysulfonic acid Baeyer-Villiger reaction |
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