| 固氮酶的固氮机理和其人工模拟问题的探讨 |
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| 引用本文： | 张纯喜.固氮酶的固氮机理和其人工模拟问题的探讨[J].化学进展,1997,9(2):131-139. |
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| 作者姓名： | 张纯喜 |
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| 作者单位： | （中国科学院福建物质结构研究所 福州 350002） |
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| 摘 要： | 固氮酶将N2 还原为NH3 的过程是自然界实现氮循环的重要环节。本文着重对固氮酶的固氮机理和其活性中心FeMo 辅基的人工模拟合成进行探讨, 其中包括FeMo蛋白中的质子和电子的传递, FeMo 辅基对N2 的活化方式,Mo 原子的作用, 固氮活性的测试。最后还就固氮酶的活性中心FeMo 辅基的人工模拟合成进行了探讨。
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| 关 键 词： | 固氮酶 固氮机理 固氮活性 FeMo辅基 人工模拟合成 |
| 收稿时间： | 1996-04-01 |
| 修稿时间： | 1996-09-01 |
Discussion for Mechanism of Nitrogen Fixation in Nitrogenase and Its Synthesis of Manual Simulation |
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| Zhang Chunxi.Discussion for Mechanism of Nitrogen Fixation in Nitrogenase and Its Synthesis of Manual Simulation[J].Progress in Chemistry,1997,9(2):131-139. |
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| Authors: | Zhang Chunxi |
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| Institution: | (Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences, Fuzhou 350002, China) |
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| Abstract: | The process of nitrogen fixation in nitrogenase is an essential element for the nitrogen cycle in nature.In this article,the emphasis is on the mechanism of nitrogen fixation and the synthesis of manual simulation of FeMo cofactor.Contents include:transfer of proton and electron in FeMo protein,model of the dinitrogen activation by FeMo cofactor,function of molybdenum atom in nitrogenase,measure for activity of nitrogen fixation.The synthesis of manual simulation of FeMo cofactor is also discussed. |
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| Keywords: | nitrogenase mechanism of nitrogen fixation activity of nitrogen fixation FeMo cofactor synthesis of manual simulation |
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