| 两相催化——均相催化多相化新进展 |
| |
| 引用本文： | 郑晓来,蒋景阳,王兵,金子林.两相催化——均相催化多相化新进展[J].化学进展,1997,9(2):111-122. |
| |
| 作者姓名： | 郑晓来 蒋景阳 王兵 金子林 |
| |
| 作者单位： | 大连理工大学化工学院精细化工国家重点实验室 |
| |
| 基金项目： | 国家自然科学基金,中国石化总公司基础研究基金 |
| |
| 摘 要： | 评述了水溶性膦配体和两相催化研究领域的进展, 探讨了固载水相催化、温控相转移催化和氟两相体系等新型两相催化体系。两相催化在烯烃的氢甲酰化反应、不饱和化合物的加氢反应以及其它有机反应中获得了广泛的应用。
|
| 关 键 词： | 两相催化 水溶性膦配体 金属有机配合物 加氢甲酰化 加氢反应 |
| 收稿时间： | 1996-04-01 |
| 修稿时间： | 1996-10-01 |
Two-Phase Catalysis Recent Advances in the Heterogenization of Homogeneous Catalysis |
| |
| Zheng Xiaolai,Jiang Jingyang,Wang Bing,Jin Zilin.Two-Phase Catalysis Recent Advances in the Heterogenization of Homogeneous Catalysis[J].Progress in Chemistry,1997,9(2):111-122. |
| |
| Authors: | Zheng Xiaolai Jiang Jingyang Wang Bing Jin Zilin |
| |
| Institution: | (State Key Laboratory of Fine Chemicals, School of Chemical Engineering,Dalian University of Technology, Dalian 116012, China) |
| |
| Abstract: | Recent developments in the chemistry of water soluble phosphines and two phase catalysis are discussed, including several novel two phase catalytic systems that are supported aqueous phase catalysis, thermoregulated phase transfer catalysis, and fluorous biphase system. Numerous applications of two phase catalysis to hydroformylation, hydrogenation and other organic reactions are also described. |
| |
| Keywords: | two phase catalysis water soluble phosphines organometallic complexes hydroformylation hydrogenation |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《化学进展》浏览原始摘要信息 |
| 点击此处可从《化学进展》下载免费的PDF全文 |
|
