An efficient one-pot asymmetric synthesis of biaryl compounds via Diels-Alder/retro-Diels-Alder cascade reactions |
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| Authors: | Liu Yongxiang Lu Kui Dai Mingji Wang Kai Wu Wanqing Chen Jiahua Quan Junmin Yang Zhen |
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| Affiliation: | Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education and Beijing National Laboratory for Molecular Science (BNLMS), College of Chemistry, Laboratory of Chemical Genomics, Shenzhen Graduate School, China. |
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| Abstract: | [reaction: see text] A single-step chirality transfer method for the synthesis of axially chiral biaryl compounds by construction of the second aromatic ring via a Diels-Alder/retro-Diels-Alder cascade reaction is reported. This methodology should find broad application in the synthesis of natural products and asymmetric catalysts. |
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