| 二环戊二烯基钛烴氧基衍生物的合成和性能研究 |
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| 引用本文： | 吴绍祖,周耀坤.二环戊二烯基钛烴氧基衍生物的合成和性能研究[J].高等学校化学学报,1983,4(1):127. |
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| 作者姓名： | 吴绍祖 周耀坤 |
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| 作者单位： | 兰州大学化学系 |
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| 摘 要： | 二环戊二烯基二氯化钛与脂肪醇的反应是非常复杂的,由于反应体系不同,所得的产物也不同,且产物又不稳定1-3]。
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| 收稿时间： | 1981-06-30 |
SYNTHESIS AND SOME PROPERTIES OF THE REACTION PRODUCTS OF TITANOCENE DICHLORIDE WITH SOME AROMATIC ALCOHOLS |
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| Wu Shaozu,Zhou Yaokun.SYNTHESIS AND SOME PROPERTIES OF THE REACTION PRODUCTS OF TITANOCENE DICHLORIDE WITH SOME AROMATIC ALCOHOLS[J].Chemical Research In Chinese Universities,1983,4(1):127. |
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| Authors: | Wu Shaozu Zhou Yaokun |
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| Institution: | Department of Chemistry, Lanzhou University, Lanzhou |
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| Abstract: | Some dicyclopentadienyl compounds of titanium, Cp2Ti(OCH2C6H5) Cl, Cp3TiOCH(CH3)C6H5]Cl and Cp2Ti(OCH2CH2C6H5)Cl, have been synthesized with good yields. They react readily with electrophilic reagents such as hydrogen chloride, acetyl chloride or benzoyl chloride and thionyl chloride, to give dicyclopentadienyl titanium dichloride. The reactions of these compounds with water, alcohol and tetrahydrofuran afforded the corresponding complexes. The IR spectra and the thermal stability of these compounds have also been studied. |
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