Radical reaction of ethyl orthoacetate with 3,3,3-trifluoropropene |
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| Authors: | I I Khatuntsev E V Pastushenko A B Terent'ev |
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| Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Summary The reaction of 3,3,3-trifluoropropene with ethyl orthoacetate leads to the formation of an acetate CH3C(O)OCH(CH3)CH2CH2CF3 and a ketone CH3C(O)CH2CH(CF3)CH2CH2CF3. A reaction mechanism is proposed which involves rearrangement of the radicals CR3C(OC2H5)2OCH(CH3) (CH2CHCF3)
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with 1,7- and 1,5-migration of an H atom and stabilization by fragmentation.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1583–1586, July, 1986. |
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