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N-heterocyclic carbenes in gold catalysis
Authors:Marion Nicolas  Nolan Steven P
Institution:Institute of Chemical Research of Catalonia (ICIQ), Av. Pa?sos Catalans 16, 43007 Tarragona, Spain.
Abstract:The appealing properties of N-heterocyclic carbenes (NHC) as ancillary ligands and the high potential of gold as an organometallic catalyst have made their encounter inevitable. Still in its infancy, NHC-gold catalysis is nevertheless growing rapidly. In this tutorial review, catalytic transformations involving NHC-containing gold(i) and gold(iii) complexes are presented. Particular attention is drawn to the versatility and selectivity of these catalysts.
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