Palladium-catalyzed enantioselective allylic substitution by chiral p,n-heterodonor ligands |
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| Authors: | Sang-Han Kim Xiao-Feng Guo Geon-Joong Kim |
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| Affiliation: | (1) Department of Chemical Engineering, Inha University,, Incheon 402-751, Korea;(2) Department of Chemical Engineering, Inha University,, Incheon 402-751, Korea;(3) Department of Chemical Engineering, Inha University,, Incheon 402-751, Korea |
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| Abstract: | Summary Chiral P,N-heterodonor ligands are effective in the enantioselective allylic substitution of 1,2-diphenyl-2-propenyl acetate with dimethylmalonate. The reactions are conveniently carried out at ambient temperature. The excellent levels of enantiomeric excess up to 98% were obtained in good conversion. |
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| Keywords: | chiral P N- heterodonor ligand enantioselective allylic substitution Pd-catalyzed |
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