Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of alpha,beta-unsaturated carbonyl compounds |
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| Authors: | Anada Masahiro Tanaka Masahiko Suzuki Kanami Nambu Hisanori Hashimoto Shunichi |
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| Institution: | Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo, Japan. |
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| Abstract: | The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of alpha,beta-unsaturated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh2(pfb)4, proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields. |
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