From isocyanides to trichloropyruvamides: application to a new preparation of oxamide derivatives |
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Authors: | Laurent El Kaim Laetitia Gaultier Laurence Grimaud Emilie Vieu |
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Affiliation: | Laboratoire Chimie et Procédés, Ecole Nationale Supérieure de Techniques Avancées, 32 Bd Victor, 75015 Paris, France |
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Abstract: | Isocyanides react readily with trichloroacetic acid anhydride forming stable hydrates of trichloropyruvamides. These compounds are valuable intermediates for obtaining oxamides by reaction with TMSCl/NEt3 followed by addition of an amine. |
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Keywords: | Trichloromethyl Amide Pyruvamide Isocyanides |
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