Enantioselective synthesis induced by chiral organic-inorganic hybrid silsesquioxane in conjunction with asymmetric autocatalysis |
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| Authors: | Tsuneomi Kawasaki |
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| Affiliation: | Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan |
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| Abstract: | 5-Pyrimidyl alkanol with up to 96% ee was formed using chiral organic-inorganic hybrid silsesquioxane in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, in conjunction with asymmetric autocatalysis. |
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| Keywords: | Asymmetric induction Asymmetric synthesis Asymmetric autocatalysis Chiral hybrid silsesquioxane |
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