Stereoselective synthesis of the C9-C19 lactone-dipropionate fragment of calyculin C |
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| Authors: | Kaisa Karisalmi |
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| Affiliation: | Laboratory of Organic Chemistry, Helsinki University of Technology, PO Box 6100, FIN-02015 HUT, Finland |
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| Abstract: | A highly diastereoselective synthesis of the title fragment of calyculin C has been developed based on an internal asymmetric induction between a chiral aldehyde and Z-crotyl trifluorosilane. |
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| Keywords: | Aldol reactions Crotylation Diastereoselectivity Natural products Stereoselective synthesis |
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