An environmentally benign and practical synthesis of sugar orthoesters promoted by potassium fluoride |
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| Authors: | Shin-ichiro Shoda Masashi Moteki Ryuko Izumi Masato Noguchi |
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| Institution: | Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Aoba 6-6-07, Sendai 980-8579, Japan |
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| Abstract: | An extremely practical method for synthesis of sugar orthoesters has been developed without using any organic amines or heavy metals as additives. Various sugar orthoesters were prepared in good yields by the reaction of an acylated glycosyl bromide and an alcohol in the presence of potassium fluoride. |
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| Keywords: | Sugar orthoesters Potassium fluoride Glycosyl bromides |
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