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An efficient synthesis of 4H,5H-pyrano[3,4-c]pyran-4,5-diones from a suitably functionalized 2H-pyran-2-one
Authors:Diptesh Sil
Affiliation:Medicinal and Process Chemistry Division, Central Drug Research Institute, Lucknow 226001, India
Abstract:An efficient synthesis of ethyl 7-aryl-2-methyl-4H,5H-pyrano[3,4-c]pyran-4,5-dione-1-carboxylate 5, and ethyl 6-aryl-3-cyano-2H-pyran-2-one-4-acetate 6 has been delineated by reaction of suitably functionalized 2H-pyran-2-ones 1 with ethyl acetoacetate 2.
Keywords:Pyrano[3,4-c]pyran-4,5-dione   2H-pyran-2-one   Ethyl acetoacetate   Reaction mechanism
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