A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands |
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| Authors: | Catherine Anne McNamara Mark Bradley |
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| Institution: | a Department of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, UK
b Johnson Matthey Research and Technology, PO Box 1, Belasis Avenue, Billingham, Cleveland TS23 1LB, UK |
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| Abstract: | Sharpless asymmetric dihydroxylation ligands were synthesized using a triazine spacer group in two, high yielding steps from cheap, readily available starting materials. The ligands, gave good enantioselectivities in the asymmetric dihydroxylation of alkenes and may provide a very economic alternative to current systems. |
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| Keywords: | Triazine Sharpless Dihydroxylation |
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