Rhodium-catalyzed carbonyl allylations by allylic alcohols with tin(II) chloride |
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| Authors: | Yoshiro Masuyama Yusuke Kaneko Yasuhiko Kurusu |
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| Institution: | Department of Chemistry, Sophia University, 7-1 Kioicho, Chiyoda-ku, Tokyo 102-8554, Japan |
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| Abstract: | Rhodium complexes such as RhCl(cod)]2, Rh(cod)2]BF4, and Rh(cod)(CH3CN)2]BF4 function as catalysts for carbonyl allylations by allylic alcohols with 1 equimolar amount of tin(II) chloride to each allylic alcohol and aldehyde in THF at 50 °C to produce the corresponding homoallylic alcohols. |
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| Keywords: | Nucleophilic addition Carbonyl allylation π-Allylrhodium Tin(II) chloride |
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