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A convenient synthesis of high-loaded palladium(II) ROMP polymers
Authors:D. Christopher Braddock  David Chadwick
Affiliation:a Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK
b Department of Chemical Engineering, Imperial College, London, UK
Abstract:Bis[1-(5-norbornen-2-yl)butan-1,3-dionato]palladium(II) was conveniently prepared from 5-acetoacetyl-2-norbornene and sodium tetrachloropalladate. The former could be subjected to ROMP to give a highly-loaded palladium(II) ROMP polymer with a palladium loading of 23% by weight.
Keywords:Palladium(II)   ROMP   ROMP polymer
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