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Application of polymer-supported triphenyl phosphine in the palladium-catalyzed cyanation reaction under microwave conditions
Authors:Rajiv R. Srivastava  Scott E. Collibee
Affiliation:Department of Combinatorial/Parallel Synthesis Albany Molecular Research, Inc., PO Box 15098, Albany, NY 12212-5098, USA
Abstract:A variety of aryl nitriles were prepared in excellent yields from the palladium acetate catalyzed coupling of aryl halides with Zn(CN)2 using polymer-supported triphenyl phosphine as the ligand and dimethylformamide as solvent under microwave irradiation conditions.
Keywords:Aryl halides   Nitriles   Palladium   Heterogeneous catalyst   Microwave irradiation
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