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Pyrrole synthesis using a tandem Grubbs’ carbene-RuCl3 catalytic system |
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| Authors: | Nicolai Dieltiens David De Vos Renata Drozdzak |
| Institution: | a Research group SynBioC, Department of Organic Chemistry, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, B-9000 Ghent, Belgium b Division of Organometallics and Catalysis, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 (S-3), B-9000 Ghent, Belgium |
| Abstract: | A straightforward pyrrole synthesis from diallylamines is developed by using a tandem catalyst system leading to ring-closing metathesis with the second generation Grubbs’ catalyst (10%) followed by dehydrogenation in the presence of RuCl3 × H2O (2%). |
| Keywords: | Ring-closing metathesis Pyrrole synthesis |
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