Barium dichromate [BaCr2O7], a mild reagent for oxidation of alcohols to their corresponding carbonyls in non-aqueous polar aprotic media |
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| Authors: | Enayatollah Mottaghinejad E Shaafi Z Ghasemzadeh |
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| Institution: | Department of Chemistry, Azad University of Iran-Rey Branch, PO Box 19395-5858 Tehran, Iran |
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| Abstract: | Barium dichromate is used as a mild oxidizing agent for the selective conversion of primary and secondary alcohols to their corresponding aldehydes and ketones, respectively. Over-oxidation does not occur and primary alcohols undergo oxidation to the aldehyde. Primary and secondary benzylic alcohols are oxidized faster and more efficiently. |
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| Keywords: | Barium dichromate Oxidation Oxidizing agent Non-aqueous media |
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