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Allylation of epoxides with allylic indium reagents
Authors:Tsunehisa Hirashita  Kazuma Mitsui  Yousuke Hayashi  Shuki Araki
Affiliation:Omohi College, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
Abstract:Allylindium sesquihalide reacts with epoxide to give homoallyl alcohol via a 1,2-shift reaction. In contrast, allylindate gives the ring-opening product without rearrangement.
Keywords:Indium   Ate complex   Epoxide   Allylation
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