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Sulfenylation of nitroalkanes and hydroxyaryls
Authors:Guillermo A BlancoMaria T Baumgartner
Institution:INFIQC, Dpto. Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba 5000, Argentina
Abstract:The sulfenylation of nitroalkanes and hydroxyaryls in DMSO using aryl disulfides as sulfenylating reagents was studied. The corresponding arylthionitroalkanes and arylthiohydroxyaryls were obtained in moderate to good yields in very mild conditions, thus improving the reported procedures for the synthesis of these compounds.
Keywords:Sulfenylation  Disulfides  Nitroalkanes  Hydroxyaryls  Dimethylsulfoxide
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