Redox reactions between organic halo-compounds and ferrous cations in isopropanol |
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| Authors: | Liliane Wilputte-Steinert |
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| Institution: | (1) Chimie Organique Physique, Faculté des Sciences, Université Libre de Bruxelles, Avenue F.D. Roosevelt 50, B-1050 Brussels, Belgium |
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| Abstract: | Summary Halo-compounds of which the half-wave reduction potential is equal to or less negative than that of carbon tetrachloride, are reduced by tetrachloroferrate(II) anions. The bimolecular rate constants measured at 250 in isopropanol are 2 × 10–5 M–1 s–1 and 1 × 10–4 M–1 s–1 respectively for CCl4 and CCl3CO2Me. |
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