Simultaneous derivative spectrophotometric determination of thorium and uranium in a micellar medium |
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Authors: | Agnihotri N K Singh V K Singh H B |
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Affiliation: | Department of Chemistry, University of Delhi, Delhi 110007, India |
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Abstract: | Derivative photometric methods for trace analysis of Th(IV) and UO2(II), and their simultaneous determination in mixtures using 5,8-dihydroxy-1,4-naphthoquinone in a micellar medium are reported. Molar absorptivity and Sandell's sensitivity of 1:2 Th(IV) and 1:1 UO2(II) complexes at their λmax, 614.5 nm and 637.0 nm are, 1.19 × 104 1/mol/cm and 1.12 × 104 1/mol/cm and 1.95 × 10−2 μg/cm2 and 2.13 × 10−2 μg/cm2 μg/cm2, respectively. Calibration graph is linear over the range 9.28 × 10−2−18.56 μg/ml of Th(IV) and 9.52 × 10−2−19.04 μg/ml of UO2(II). Though presence of Th(IV) and UO2(II) causes interference in each others determination, 9.28 × 10−1−9.28 μg/ml Th(IV) and 9.52 × 10−1−9.52 μg/ml UO2(II) when present together, can be simultaneously determined using derivative spectra. |
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