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Synthesis, growth and characterization of l-valine cadmium chloride monohydrate—A novel semiorganic nonlinear optical crystal
Authors:P. Maadeswaran  J. Chandrasekaran
Affiliation:a Department of Physics, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore 641020, Tamil Nadu, India
b Department of Physics, K.S. Rangasamy College of Technology, Tiruchengode 637215, Tamil Nadu, India
Abstract:Single crystals of l-valine cadmium chloride monohydrate (LVCC), a novel semiorganic nonlinear optical material were synthesized and grown from aqueous solution by slow evaporation method at room temperature. The powder X-ray diffraction pattern and FT IR spectrum analysis confirmed the formation of the new crystal. LVCC has good optical transmission in the entire visible region, which is an essential requirement for a nonlinear crystal. The thermal studies reveal that the material has good thermal stability. The LVCC crystal was characterized by energy dispersive X-ray analysis. The optical second harmonic generation conversion efficiency of LVCC was determined using Kurtz powder technique.
Keywords:Characterization   Growth from solution   Semiorganic   Nonlinear optical crystals
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