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Lipase-catalyzed reactions in ionic liquids
Authors:Madeira Lau R  van Rantwijk F  Seddon K R  Sheldon R A
Affiliation:Laboratory of Organic Chemistry and Catalysis, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands.
Abstract:[reaction:see text] Candida antarctica lipase was shown to catalyze alcoholysis, ammoniolysis, and perhydrolysis reactions using the ionic liquids 1-butyl-3-methylimidazolium tetrafluoroborate or hexafluorophosphate as reaction media. Reaction rates were generally comparable with, or better than, those observed in organic media.
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