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| 含2，2′-联吡啶配体簇合物的合成、晶体结构及非线性光学性质 | |
| 引用本文： | 胡月华,王玉晓,周建良,宋瑛林,李一志,郑和根,忻新泉.含2，2′-联吡啶配体簇合物的合成、晶体结构及非线性光学性质[J].无机化学学报,2003,19(2):215-218. |
| 作者姓名： | 胡月华 王玉晓 周建良 宋瑛林 李一志 郑和根 忻新泉 |
| 作者单位： | 1. 黄山学院化学系,黄山,245021 2. 哈尔滨工业大学应用物理系,哈尔滨,150001 3. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 |
| 基金项目： | 国家自然科学基金资助项目(No.20171020)，国家自然科学基金重大项目资助(No.90101028) |
| 摘 要： | The Cluster compound Cu3BrWOS3(bipy)2] was synthesized by reaction of (NH4)2WOS3， CuBr， 2，2′- bipyridine and n-Bu4NBr at room temperature and characterized by IR， UV and elemental analyses. The structure of Cu3BrWOS3(bipy)2] was determined by single crystal X-ray diffraction revealing that the cluster consist of a nest -shaped core. The W atom is tetrahedrally coordinated by three S atoms and one O atom. There are two types of copper atoms in the WOS3Cu3 aggregate： two copper atoms are tetrahedrally coordinated and another copper atom is trigonally coordinated. The nonlinear optical properties were studied with an 8ns pulsed laser at 532nm. Its optical responses to the incident light exhibit considerably optical absorptive and strong self-focusing effect with α2=0.90×10-10m·W-1， n2=2.72×10-18m2·W-1. CCDC： 196348. |
| 关 键 词： | 晶体结构 非线性光学性质 合成 金属簇合物 Z-扫描 |
| 修稿时间： | 2002年11月1日 |
Synthesis, Crystal Structure and Nonlinear Optical Properties of Cluster Compound Containing 2, 2'-Bipyridine as Ligand |
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| HU Yue-Hu,WANG Yu-Xiao,ZHOU Jian-Liang,SONG Ying-Lin,LI Yi-Zhi,ZHENG He-Gen and XIN Xin-Quan.Synthesis, Crystal Structure and Nonlinear Optical Properties of Cluster Compound Containing 2, 2''''-Bipyridine as Ligand[J].Chinese Journal of Inorganic Chemistry,2003,19(2):215-218. | |
| Authors: | HU Yue-Hu WANG Yu-Xiao ZHOU Jian-Liang SONG Ying-Lin LI Yi-Zhi ZHENG He-Gen and XIN Xin-Quan |
| Abstract: | |
| Keywords: | crystal structure nonlinear optics synthesis metal cluster Z-scan |
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