纳米纤锌矿氮化硼的同步辐射真空紫外反射光谱与光学性质

对冲击波法合成的纳米纤锌矿氮化硼（ｗＢＮ）进行了同步辐射真空紫外区的反射光谱测量，得到波长范围１００一２４０ｎｍ区间的反射光谱．利用Ｋｒａｍｅｒｓ－Ｋｒｏｎｉｇ关系计算获得了它的光学常数和介电函数谱，并导出了光电导谱．获得了纳米ｗＢＮ的光学禁带宽度实验值，为８．７±０．５ｅＶ．将以上结果和最新的理论计算进行了比较．观察到了经不同退火温度处理的纳米ｗＢＮ样品结构及尺寸变化对反射光谱和光学性质的影响． 关键词：

REFLECTANCE SPECTRUM AND OPTICAL PROPERTIES OF NANO-wBN IN THE VUV REGION OF SYNCHROTRON RADIATION

The reflectance spectrum of different wBN was measured. The sample were prepared by shock-wave method and heat-treated at 100℃ and 500℃. The measurement was performed in the wavelength range of 100-240nm at the time-resolved spectroscopy station of National Synchrotron Radiation Laboratory in Hefei. The optical constants of wBN have been determined in the VUV region by applying the Kramers-Kronig relation to normal incidence reflectance data. It was found that the average value of optical band gap determined from these constants is ８．７±０．５eV. The dielectric constants, optical conductivity of wBN were also obtained. The effet of the charges of particle size and structure of the nanometer-sized wBN on the optical reflectance spectrum were further studied.