Constraints on Contact Angles for Multiple Phases in Thermodynamic Equilibrium |
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Authors: | Blunt Martin J |
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Institution: | T. H. Huxley School, Imperial College, Prince Consort Road, London, SW7 2BP, United Kingdom |
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Abstract: | For three or more fluid phases in thermodynamic equilibrium and in contact with a solid surface, the Young equation can be used to find relations between the contact angles for different pairs of fluids. For an n-fluid-phase system, n(n-1)/2 contact angles can be defined, but there are (n-1)(n-2)/2 constraints between them, leaving only n-1 independent values of the contact angle. These constraints are very powerful in limiting and determining possible types of wetting behavior. The consequences are discussed for three- and four-phase flow. They have important applications for the understanding of gas injection processes in petroleum reservoirs. Copyright 2001 Academic Press. |
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