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Ag复合对LaCoO_3陶瓷热电性能的影响
引用本文:柳 雪,宋 英,牛丽丹,王福平.Ag复合对LaCoO_3陶瓷热电性能的影响[J].无机化学学报,2010,26(1):157-160.
作者姓名:柳 雪  宋 英  牛丽丹  王福平
作者单位:哈尔滨工业大学化工学院,哈尔滨,150001
摘    要:<正>0引言热电材料是利用热电效应实现电能和热能相互转化的功能材料,在废热发电和无氟制冷等方面有广泛的应用前景。其中氧化物热电材料是近年来备

关 键 词:LaCoO3    Ag复合    高分子网络凝胶法    热电性能

Effects of Ag Addition on Thermoelectric Properties of LaCoO3 Ceramics
LIU Xue,SONG Ying,NIU Li-Dan and WANG Fu-Ping.Effects of Ag Addition on Thermoelectric Properties of LaCoO3 Ceramics[J].Chinese Journal of Inorganic Chemistry,2010,26(1):157-160.
Authors:LIU Xue  SONG Ying  NIU Li-Dan and WANG Fu-Ping
Institution:School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001,School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001,School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001 and School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001
Abstract:LaCoO_3 powder was prepared by a polyaerylamide gel method,and then composed with Ag by liquid phase method.LaCoO_3/xAg(x=0,0.05,0.10,0.20) composite ceramics were sintered by a traditional pressureless sintering technique after being shaped through cold isostatic pressing.Effects of Ag addition on thermoelectric properties of LaCoO_3 ceramics were investigated at room temperature.The results indicate that Ag particles are dispersed in the LaCoO_3 matrix as the second phase,the electrical conductivity(σ) and thermal conductivity(κ) of the composites are larger than those of LaCoO_3,and increase with Ag content.Meanwhile,Seebeck coefficient(S) of the composites increases firstly and then decreases with increasing in Ag content.Since the enhancement of σ is more significant,the values of power factor and ZT are improved by the addition of Ag.
Keywords:LaCoO3  Ag addition  polyacrylamide gel method  thermoelectric properties
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