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White organic light-emitting devices using Zn(BTZ)2 doped with Rubrene as emitting layer
作者姓名:ZHENGJiajin  HUAYulin  YINShougen  FENGXiulan  WUXiaoming  SUNYuanyuan  LIYongfang  YANGChunhe  SHUAIZhigang
作者单位:[1]InstituteofMaterialPhysics,TianjinUniversityofTechnology,Tianjin300191,China [2]OrganicSolidsLaboratory,InstituteofChemistry,ChineseAcademyofSciences,Beijing100080,China
摘    要:Zn(BTZ)2 was synthesized from the complex reaction between zinc acetate dihydrate and 2-(2-hydroxyphenyl) benzothiazolate. Then Zn(BTZ)2 was used as main light-emitting material doped with different amounts of fluorescent dye Rubrene and fabricated a series of white organic light emitting devices. The configurations were as follows: ITO/PVK:TPD/Zn(BTZ)2:Rubrene/Al. The doping concentration of Rubrene in Zn(BTZ)2 was 1.2%, 0.12%, 0.08% and 0.05%, respectively. According to the EL spectra and CIE coordinates of the above devices, the optimum doping concentration (0.05%, weight percent) had been determined. The steady and bright white light emitting of the device with 0.05% doping concentration had been obtained, and the white emission covered a wide range of driving voltage (10--22.5 V). The CIE coordinates were (x=0.341, y=0.334) at the driving voltage of 20 V, which was very close to the equi-energy point (x=0.333, y=0.333), and the corresponding luminance and external quantum efficiency were 4048 Cd/m^2 and 0.63% (4.05 Cd/A), respectively. Lastly, we also discussed the emitting mechanisms of the material and the devices.

关 键 词:Zn(BTZ)2  红荧烯  放射层  合成方法    白光  光放射材料
收稿时间:16 March 2004

White organic light-emitting devices using Zn(BTZ)2 doped with Rubrene as emitting layer
ZHENGJiajin HUAYulin YINShougen FENGXiulan WUXiaoming SUNYuanyuan LIYongfang YANGChunhe SHUAIZhigang.White organic light-emitting devices using Zn(BTZ)2 doped with Rubrene as emitting layer[J].Chinese Science Bulletin,2005,50(6):509-513.
Authors:Jiajin Zheng  Yulin Hua  Shougen Yin  Xiulan Feng  Xiaoming Wu  Yuanyuan Sun  Yongfang Li  Chunhe Yang  Zhigang Shuai
Institution:(1) Institute of Material Physics, Tianjin University of Technology, 300191 Tianjin, China;(2) Organic Solids Laboratory, Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, China
Abstract:Zn(BTZ)2 was synthesized from the complex reaction between zinc acetate dihydrate and 2-(2-hydroxyphenyl) benzothiazolate. Then Zn(BTZ)2 was used as main light-emitting material doped with different amounts of fluorescent dye Rubrene and fabricated a series of white organic light emitting devices. The configurations were as follows: ITO/PVK:TPD/Zn(BTZ)2:Rubrene/Al. The doping concentration of Rubrene in Zn(BTZ)2 was 1.2%, 0.12%, 0.08% and 0.05% respectively. According to the EL spectra and CIE coordinates of the above devices, the optimum doping concentration (0.05% weight percent) had been determined. The steady and bright white light emitting of the device with 0.05% doping concentration had been obtained, and the white emission covered a wide range of driving voltage (10–22.5 V). The CIE coordinates were (x=0.341,y=0.334) at the driving voltage of 20 V, which was very close to the equi-energy point (x=0.333,y=0.333), and the corresponding luminance and external quantum efficiency were 4048 Cd/m2 and 0.63% (4.05 Cd/A), respectively. Lastly, we also discussed the emitting mechanisms of the material and the devices.
Keywords:white light  OLED  bis(2-(2-hydroxyphenyl)benzothia-  zolate)zinc  Rubrene  doping  
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