Facilitated transport mechanism in fixed site carrier membranes |
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Authors: | Richard D. Noble |
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Affiliation: | University of Colorado, Department of Chemical Engineering, Campus Box 424, Boulder, CO 80309 USA |
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Abstract: | Facilitated transport of gases, such as O2, has been observed for fixed site carrier membranes. Carrier-impregnated ion-exchange membranes have also been used to produce facilitated transport of CO2, H2S and olefins when the carriers are not completely mobile. The actual mechanism for this facilitated transport has not been determined previously. The facilitated transport is provided by the exchange of solute between the free solute region and the bound complexing agent combined with gradients in the free solute and complexed carrier. The ratio of mobility for exchange between the regions is the dimensionless equilibrium constant of the reversible reaction. An expression is also derived for the relationship between the effective diffusion coefficient of the complex in facilitated transport, DAB, and the diffusion coefficients for exchange between free and complexed solute, DDH and DHD. Since DAB can be determined from experimental results, DDH and DHD can be calculated. The results also show the morphology dependence of DAB. The diffusion coefficient of the free solute DA also changes with the loading of the complexing agent in the film. This morphology dependence can explain why the gas permeability can decrease when the concentration of the complexing agent increases in the membrane. |
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Keywords: | diffusion facilitated transport gas and vapor permeation gas separations theory fixed site carrier membranes |
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