Polarised raman and infrared spectra and vibrational analysis forα-naphthylamine |
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Authors: | R Shanker R A Yadav I S Singh O N Singh |
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Affiliation: | (1) Department of Physics, Banaras Hindu University, 221 005 Varanasi, India;(2) Applied Physics, Institute of Technology, Banaras Hindu University, 221 005 Varanasi, India |
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Abstract: | The Raman spectrum of polycrystalline α-naphthylamine was recorded in the region 100–4000 cm−1. Polarisation measurements were made in CS2 and CHCl3 solutions. The infrared spectrum was recorded in nujol mull in the region 200–4000 cm−1. The resolution was better than 2 cm−1 and the accuracy of the measurements was within ± 2 cm−1 for all the spectra. Vibrational assignments have been proposed for the observed frequencies. Out of the 54 normal modes of vibrations, 51 modes could be observed experimentally. |
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Keywords: | Raman spectrum infrared spectrum vibrational spectrum fundamental frequencies |
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