| (Zn，M)TiO3(M=Co，Ni，Co0.5Ni0.5)固溶体的溶胶-凝胶法合成 |
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| 引用本文： | 罗 君,张 梅,邢献然,于然波,邢奇凤,刘桂荣.(Zn，M)TiO3(M=Co，Ni，Co0.5Ni0.5)固溶体的溶胶-凝胶法合成[J].无机化学学报,2006,22(4):625-628. |
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| 作者姓名： | 罗 君 张 梅 邢献然 于然波 邢奇凤 刘桂荣 |
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| 作者单位： | 1. 北京科技大学理化系,北京,100083
2. 北京科技大学冶金与生态工程学院实验技术中心,北京,100083 |
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| 基金项目： | 中国科学院资助项目;教育部高等学校骨干教师资助计划 |
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| 摘 要： | 通过改进的溶胶-凝胶工艺在低温(800 ℃)下合成了基于钛酸锌(ZnTiO3)体系的(Zn1-xCox)TiO3、(Zn1-xNix)TiO3和Zn1-x(Co0.5Ni0.5)x]TiO3陶瓷固溶体。采用X射线衍射分析(XRD)和差示扫描量热法(DSC)等测量技术对产物进行了物相和热稳定性分析。XRD结果表明，获得单一六方相(Zn1-xCox)TiO3、(Zn1-xNix)TiO3和Zn1-x(Co0.5Ni0.5)x]TiO3时各自的固溶稳定区间为0.5 ≤ x ≤ 1.0, 0.9 ≤ x ≤ 1.0和0.8 ≤ x ≤ 1.0。与此同时，热分析结果证实，伴随钛酸锌基陶瓷体系掺杂钴量的增加，其六方相的热稳定性提高，且效果比掺杂镍更加显著。
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| 关 键 词： | 钛酸锌基陶瓷 溶胶-凝胶工艺 热稳定性 |
| 文章编号： | 1001-4861(2006)04-0625-04 |
| 收稿时间： | 2005-10-10 |
| 修稿时间： | 2005-12-23 |
Synthesis of the (Zn, M)TiO3 (M=Co, Ni, Co0.5Ni0.5) Solid Solution by a Sol-gel Route |
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| LUO Jun,ZHANG Mei,XING Xian-Ran,YU Ran-Bo,XING Qi-Feng and LIU Gui-Rong.Synthesis of the (Zn, M)TiO3 (M=Co, Ni, Co0.5Ni0.5) Solid Solution by a Sol-gel Route[J].Chinese Journal of Inorganic Chemistry,2006,22(4):625-628. |
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| Authors: | LUO Jun ZHANG Mei XING Xian-Ran YU Ran-Bo XING Qi-Feng and LIU Gui-Rong |
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| Institution: | Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083,Experimental Technology Centre of School of Metallurgical & Ecological Engineering, University of Science & Technology Beijing, Beijing 100083,Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083,Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083,Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083 and Experimental Technology Centre of School of Metallurgical & Ecological Engineering, University of Science & Technology Beijing, Beijing 100083 |
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| Abstract: | |
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| Keywords: | ZnTiO3-based ceramics sol-gel route thermal stability |
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