| 丙烯酸酯共聚物涂膜中钛螯合物的交联作用 |
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| 引用本文： | 黄志虹,严芳,张黎明,钟俊文.丙烯酸酯共聚物涂膜中钛螯合物的交联作用[J].功能高分子学报,2004,17(3):406-410. |
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| 作者姓名： | 黄志虹 严芳 张黎明 钟俊文 |
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| 作者单位： | 1. 中山大学化学与化学工程学院高分子研究所,广东,广州,510275
2. 珠海乐通化工制造有限公司,广东,珠海,519085 |
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| 基金项目： | 珠海市科委科技计划资助项目(PC200310031)，广东省自然科学基金资助项目(039184) |
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| 摘 要： | 用红外光谱、紫外光谱、差示扫描量热等手段表征了掺杂体系内钛螯舍物(Ti-Ac)与丙烯酸酯共聚物的相互作用。测试了Ti-Ac用量对涂膜耐水性、耐热性及复溶性的影响。鲒果表明。当ωTi-Ac=0．015时涂膜的吸水率可下降到1％以下。且涂膜仍保持较好的复溶性(15s)。
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| 关 键 词： | 丙烯酸酯共聚物 涂膜性能 钛螯合物 交联作用 水性油墨 |
| 文章编号： | 1008-9357(2004)03-0406-05 |
| 修稿时间： | 2003年11月14 |
Crosslinking Action of Titanium Chelate in Acrylate Copolymer Coating |
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| HUANG Zhi-hong,YAN Fang,ZHANG Li-ming,ZHONG Jun-wenPolymer Science Institute,School of Chemistry and Chemical Engineering,Zhongshan.Crosslinking Action of Titanium Chelate in Acrylate Copolymer Coating[J].Journal of Functional Polymers,2004,17(3):406-410. |
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| Authors: | HUANG Zhi-hong YAN Fang ZHANG Li-ming ZHONG Jun-wenPolymer Science Institute School of Chemistry and Chemical Engineering Zhongshan |
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| Institution: | HUANG Zhi-hong~1,YAN Fang~1,ZHANG Li-ming~1,ZHONG Jun-wen~2Polymer Science Institute,School of Chemistry and Chemical Engineering,Zhongshan |
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| Abstract: | IR, UV and DSC analyses were used to characterize the interaction of the acrylate copolymers with the titanium chelate(Ti-Ac). The effect of the chelate amount on the water resistance, heat stability and film resolubility of the copolymer film were studied. When the chelate was added (w_(Ti-Ac)=0.015), the water uptake of the resulting film was lowered to less than 1%, and the film still kept a good resolubity. |
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| Keywords: | crosslinking acrylate copolymers titanium chelate water-borne ink |
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