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IR and visible luminescence studies in the infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane |
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| Authors: | K. K. Pushpa Awadhesh Kumar R. K. Vatsa P. D. Naik K. Annaji Rao J. P. Mittal V. Parthasarathy S. K. Sarkar |
| Affiliation: | a Chemistry Division, Bhabha Atomic Research Centre, Bombay 400 085, India b Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Bombay 400 085, India |
| Abstract: | The infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane gives rise to IR and visible luminescence. Vibrationally excited parent molecules dissociate via two primary channels yielding bromine and vibrationally excited HBr. The strong visible emission observed between 350 to 750 nm has been assigned to electronically excited carbene CF2BrH. |
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