Highly enantioselective hetero-Diels-Alder reaction of Brassard diene with aromatic aldehydes |
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| Authors: | Fan Qian Lin Lili Liu Jie Huang Yaozong Feng Xiaoming Zhang Guolin |
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| Affiliation: | Key Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. |
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| Abstract: | [reaction: see text] Hetero-Diels-Alder reactions of Brassard diene with aromatic aldehydes were carried out smoothly in the presence of titanium(IV) tridentate Schiff base complexes to give the corresponding chiral delta-lactones in high enantioselectivities (up to 99% ee) under mild conditions. |
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