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Reaction of 3-acylamino- and 3-alkoxybenzo[c]pyrilium salts with hydrazine
Authors:S. L. Bogza  S. Yu. Suikov  N. M. Bogdan  K. I. Kobrakov
Affiliation:(1) Moscow A. N. Kosygin State Textile University, 117983 Moscow, Russia;(2) L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of the Ukraine, 83114 Donetsk
Abstract:The reaction of 3-acylamino- and 3-alkoxybenzo[c]pyrilium perchlorates with hydrazine has been studied. It was discovered that the direction of the recyclization of the pyran ring depends on the type of substituent in position 3 and on the ratio of reactants. Derivatives of isoquinoline and benzo-2,3-diazepine were obtained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No.10, pp. 1507–1511, October, 2004.
Keywords:benzo-2,3-diazepine  benzo[c]pyrilium  hydrazine  isoquinoline  recyclization
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