Reaction of dichlorocarbene with vinyl sulfides |
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| Authors: | R. R. Kostikov A. P. Molchanov S. V. Amosova B. A. Trofimov |
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| Affiliation: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR;(2) A. A. Zhdanov Leningrad State University, USSR |
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| Abstract: | Conclusions The reaction of dihalocarbenes with vinyl sulfides gave gem-dihalocyclopropyl sulfides. The relative activity of the sulfides toward dichlorocarbene is 5–6 times greater than that of the corresponding ethers. The theory was expressed that intermediate sulfur ylides are formed in the given reaction.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1354–1358, June, 1980. |
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