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Strong flame acceleration and detonation limit of hydrogen-oxygen mixture at cryogenic temperature
Institution:1. School of Resources & Environmental Engineering, East China University of Science and Technology, Shanghai, 200237, China;2. Warwick FIRE, School of Engineering, University of Warwick, Coventry, CV4 7AL, United Kingdom;3. Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544, United States;4. Shanghai Engineering Research Center of Coal Gasification, East China University of Science and Technology, Shanghai 200237, China;5. Center for Combustion Energy, Tsinghua University, Beijing 100084, China
Abstract:A series of experiments were carried out in a closed tube at cryogenic temperature (77 K) for hydrogen-oxygen mixtures. Flame propagation speed and overpressure were measured by optical fibers and pressure sensors, respectively. The first and second shock waves were captured in the cryogenic experiments, although the shock waves always precede the flames in all cases indicating the absence of stable detonation. However, strong flame acceleration was observed for all situations, which is consistent with the prediction by expansion ratio and Zeldovich number. Besides, the tube diameter and length are also critical for flame acceleration to supersonic. All the flames in this work accelerate drastically reaching the C-J deflagration state. But at 0.4 atm, only fast flame is formed, while at higher initial pressures, the flame further accelerates to a galloping mode manifesting a near-limit detonation, which could be indicated by the stability parameter χ.
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