Detonation development in hydrogen/air mixtures inside a closed chamber: role of a cold wall

Detonation development from a hot spot has been extensively studied, where ignition occurs earlier than that in the surrounding mixtures. It has also been reported that a cool spot can induce detonation for large hydrocarbon fuels with Negative Temperature Coefficient (NTC) behavior, since ignition could happen earlier at lower temperatures. In this work we find that even for hydrogen/air mixtures without NTC behaviors, a cold wall can still initiate and promote detonation. End-wall reflection of the pressure wave and wall heat loss introduce an exothermic center outside the boundary layer, and then autoignitive reaction fronts on both sides may evolve into detonation waves. The right branch can be further strengthened by appropriate temperature gradient near the cold wall, and exhibits different dynamics at various initial conditions. The small excitation time and the large diffusivity of hydrogen provide the possibility for detonation development within the limited space between the autoignition kernel and the cold wall. Moreover, detonation may also develop near the flame front, which may or may not co-exist with detonation waves from the cold wall. Correspondingly, wall heat flux evolution exhibits different responses to detailed dynamic structures. Finally, we propose a regime diagram describing different combustion modes including normal flame, autoignition, and detonation from the wall and/or the reaction front. The boundary of normal flame regime qualitatively agrees with the prediction by the Livengood-Wu Integral method, while the detonation development from both the end wall and the reaction front observes Zel'dovich mechanism. Compared to hydrocarbons, hydrogen is resistant to knock onset but it is more prone to superknock development. The latter mode becomes more destructive in the presence of wall heat loss. This study isolates and identifies the role of wall heat loss on a potential mechanism for superknock development in hydrogen-fueled spark-ignition engines.