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The effect of filler content on the lower yield stress of polymer composites
Authors:S L Bazhenov  G P Goncharuk  V G Oshmyan  O A Serenko
Institution:(1) Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, ul. Profsoyuznaya 70, Moscow, 117393, Russia
Abstract:The effect of the concentration of the dispersed elastic filler on the lower yield stress of matrix composites based on plastic polymers is studied. As the matrix polymers, LDPE-HDPE and LDPE-(medium-density PE) are used. The elastic filler is rubber crumb prepared by roll grinding of worn tires or by deformation grinding of ethylene-propylene-diene rubber. Irrespective of the type of filler particles and their adhesion to the polymer matrix, the lower yield stress σd of the composite is described by the linear law σd = σdm(1 ? V f ), where σdm is the lower yield stress of the polymer matrix and V f is the volume content of the filler. Analysis of the published data shows that this relationship is quite general and describes the effect of rigid inorganic particles on the lower yield stress when adhesion between the filler particles and the matrix is poor.
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