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CROSSLINKING AND COMPATIBILIZATION IN BLENDS OF POLYSTYRENE AND POLYETHYLENE
作者姓名:方征平  许承威  项义崇  吴建华  徐欢驰
作者单位:Department of Chemistry,Hangzhou University,Hangzhou 310028,China,Department of Chemistry,Hangzhou University,Hangzhou 310028,China,Department of Chemistry,Hangzhou University,Hangzhou 310028,China,Department of Chemistry,Hangzhou University,Hangzhou 310028,China,Department of Chemistry,Hangzhou University,Hangzhou 310028,China
基金项目:The project is supported by the National Natural Science Foundation of China.
摘    要:This paper investigated the influences of butadiene rubber (BR) and dicumylperoxide (DCP) on thermal and rheological behaviour, morphology and mechanical proper-ties of PS/LLDPE/SBS blend. Addition of DCP alone was found to decrease the mechanicalproperties of PS/LLDPE/SBS blend due to the decomposition of PS. When BR was addedtogether with DCP, it is found that the co-crosslinking of BR, SBS and PE takes place,and the decomposition of PS is reduced simultaneously because of the consumption of thefree radicals in the crosslinking process. Synergism was thus realised which resulted in theimprovement of the ductility of blend.

收稿时间:1997-02-03

CROSSLINKING AND COMPATIBILIZATION IN BLENDS OF POLYSTYRENE AND POLYETHYLENE*
FANG Zhengping,XU Chengwei,XIANG Yichong,WU Jianhua,XU Huanchi.CROSSLINKING AND COMPATIBILIZATION IN BLENDS OF POLYSTYRENE AND POLYETHYLENE[J].Chinese Journal of Polymer Science,1998,0(3):207-213.
Authors:FANG Zhengping  XU Chengwei  XIANG Yichong  WU Jianhua  XU Huanchi
Institution:Department of Chemistry; Hangzhou University; Hangzhou 310028; China
Abstract:This paper investigated the influences of butadiene rubber (BR) and dicumylperoxide (DCP) on thermal and rheological behaviour, morphology and mechanical proper-ties of PS/LLDPE/SBS blend. Addition of DCP alone was found to decrease the mechanicalproperties of PS/LLDPE/SBS blend due to the decomposition of PS. When BR was addedtogether with DCP, it is found that the co-crosslinking of BR, SBS and PE takes place,and the decomposition of PS is reduced simultaneously because of the consumption of thefree radicals in the crosslinking process. Synergism was thus realised which resulted in theimprovement of the ductility of blend.
Keywords:Polystyrene  Polyethylene  Blends  Compatibilization  Crosslinking
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