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A composite proton-conducting membrane based on a poly(vinylidene)fluoride-poly(acrylonitrile), PVdF-PAN blend
Authors:M.?A.?Navarra,S.?Panero,B.?Scrosati  author-information"  >  author-information__contact u-icon-before"  >  mailto:scrosati@uniroma.it"   title="  scrosati@uniroma.it"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author
Affiliation:(1) Dipartimento di Chimica, Università La Sapienza, 00185 Roma, Italy
Abstract:This paper reports on the synthesis and the properties of a new microporous, composite proton-conducting gel membrane, formed by swelling a poly(vinylidene)fluoride- poly(acrylonitrile), PVdF-PAN blend-based matrix containing a dispersed Al2O3 ceramic filler with aqueous acid solutions. We show that this membrane has a high and stable conductivity, a proton transport not critically influenced by the relative humidity level, and a projected low cost. Tests in a methanol-air laboratory cell also demonstrate that the membrane is basically suitable for application in direct methanol fuel cells.
Keywords:Membrane  Proton conductivity  Fuel cells
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