| Synthesis and Crystal Structure of ［Na（DB18C6）（CH_3OH）］_2Mo_6O_（19）·（DB18C6）·（CH_3OH） |
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| 引用本文： | Zhou Yin-Zhuang, Tu Shu-Jie, Jin Xiang-Lin, Liu Shun-Cheng(Department of Chemistry,Capital Normal University,Beijing 100037)(Institute of Physical Chemistry,Beijing University,Beijing 100871)(Experimental Center,Capital Normal University,Beijing 10003. Synthesis and Crystal Structure of ［Na（DB18C6）（CH_3OH）］_2Mo_6O_（19）·（DB18C6）·（CH_3OH）[J]. 结构化学, 1995, 0(2) |
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| 作者姓名： | Zhou Yin-Zhuang Tu Shu-Jie Jin Xiang-Lin Liu Shun-Cheng(Department of Chemistry Capital Normal University Beijing 100037)(Institute of Physical Chemistry Beijing University Beijing 100871)(Experimental Center Capital Normal University Beijing 10003 |
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| 作者单位： | Zhou Yin-Zhuang; Tu Shu-Jie; Jin Xiang-Lin; Liu Shun-Cheng(Department of Chemistry，Capital Normal University，Beijing 100037)(Institute of Physical Chemistry，Beijing University，Beijing 100871)(Experimental Center，Capital Normal University，Beijing 10003 |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｎａ（ＤＢ１８Ｃ６）（ＣＨ_３ＯＨ）］_２Ｍｏ_６Ｏ_（１９）·（ＤＢ１８Ｃ６）·（ＣＨ_３ＯＨ）￥ＺｈｏｕＹｉｎ－Ｚｈｕａｎｇ；ＴｕＳｈｕ－Ｊｉｅ；ＪｉｎＸｉａｎｇ－Ｌｉｎ；ＬｉｕＳｈｕｎ－...
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Synthesis and Crystal Structure of [Na(DB18C6)(CH_3OH )]_2 Mo_6O_(19)·(DB18C6)·(CH_3OH) |
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| Zhou Yin-Zhuang, Tu Shu-Jie, Jin Xiang-Lin, Liu Shun-Cheng. Synthesis and Crystal Structure of [Na(DB18C6)(CH_3OH )]_2 Mo_6O_(19)·(DB18C6)·(CH_3OH)[J]. Chinese Journal of Structural Chemistry, 1995, 0(2) |
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| Authors: | Zhou Yin-Zhuang Tu Shu-Jie Jin Xiang-Lin Liu Shun-Cheng |
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| Abstract: | The preparation method of [Na ( DB18C6) (CH_3OH )]_2Mo_6O_(19)·(DB18C6)·(CH_3OH) , where DB18C6 is dibenzo-18-crown-6, is described. Thecrystal and molecular structure of the title complex has been determined crystallographically. The title complex crystallizes in the monoclinic system,space group P2_1/c ,a=18. 727(6) ,b=19. 555(6) , c=22. 827(7) ,β=112. 84(3)°, V=7704(4) ￣3 ,M_r = 2102. 9 , Z = 4 , F (000 ) = 4224 , μ= 1 . 028 mm ￣(-1), D_c = 1.813 g/cm￣3 . final R =0. 075 and R_w= 0. 078 based on 4463 observed reflections with F>6. 0σ(F) . The complex consists of [Mo_6O_(19)]￣(2-) ,[Na(DB18C6)]￣+ and CH_3OH, which are linked by long distance interaction through O-Na-O bond. |
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| Keywords: | synthesis crystal structure crown ether isopoly oxomolybdate |
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