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Crystal structure of Ba(VUO6)2
Authors:E. V. Alekseev  E. V. Suleimanov  E. V. Chuprunov  G. K. Fukin
Affiliation:(1) N. I. Lobachevskii Nizhnii Novgorod State University, Russia;(2) G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod
Abstract:The crystal structure of Ba(VUO6)2 was determined by X-ray diffraction at 243 K: monoclinic crystal system, space group P21/c, unit cell parameters a=6.4992(6) Å, b=8.3803(8) Å, c=10.4235(9) Å, beta=104.749(2) °, Z=2. The structure contains close-packed [VUO6]2infindelta- layers formed by the dimers of the flattened U2O12 pentagonal bipyramids and by the dimers of V2O8 square pyramids. The neighboring layers are bound by the statistically distributed barium atoms.Original Russian Text Copyright © 2004 by E. V. Alekseev, E. V. Suleimanov, E. V. Chuprunov, and G. K. FukinTranslated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 544–548, May–June 2004.
Keywords:barium uranovanadate  crystal structure  X-ray diffraction analysis  uranyl  dehydration  structural rearrangements
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