2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole-based donor-acceptor type copolymers for photovoltaic cells |
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Authors: | Eunjae Jeong Gi-hwan KimIn Hwan Jung Pyeongsu Jeong Jin Young Kim Han Young Woo |
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Affiliation: | a Department of Nanofusion Engineering, Pusan National University, Miryang 627-706, Republic of Korea b Department of Cogno-Mechatronics Engineering (WCU), Pusan National University, Miryang 627-706, Republic of Korea c Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Banyeon-ri 194, Ulsan 689-798, Republic of Korea d Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea |
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Abstract: | Alternating donor-acceptor type copolymers, poly[{5,11-di(9′-heptadecanyl)indolo[3,2-b]carbazole}-alt-{2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole-5,5′-diyl}] (PIC-TZ) and poly[{6,6′,12,12′-tetraoctylindeno[1,2-b]fluorene}-alt-{2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole-5,5′-diyl}] (PIF-TZ), were synthesized and examined for applications in polymeric photovoltaic cells. The polymers have a fused coplanar main backbone with good planarity for intermolecular packing and high charge mobility. The indolocarbazole and indenofluorene units contain two or four binding sites for alkyl substituents that have pronounced solution processiblity compared to the carbazole and fluorene moieties. The number-average molecular weights (Mn) of the synthesized polymers were determined to be 11,000 g/mol (PDI = 2.27) for PIC-TZ, and 17,000 g/mol (PDI = 1.77) for PIF-TZ. The optical band gap of PIC-TZ and PIF-TZ in film was determined to be 2.14 eV and 2.21 eV, respectively, and an electrochemical study confirmed the desirable HOMO/LUMO levels of the copolymers, which enabled efficient electron transfer and a high open circuit voltage (VOC) when blending them with fullerene derivatives. The space charge limited current mobility measurements showed a hole mobility of 10−3 cm2 V−1 s−1 for the copolymers. When the polymers were blended with [6,6]phenyl-C61-butyric acid methyl ester (PCBM), PIC-TZ showed the best performance with VOC, short-circuit current and power conversion efficiency of 0.86 V, 4.16 mA/cm2 and 1.64%, respectively, under AM 1.5G illumination conditions (100 mW cm−2). |
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Keywords: | Polymer solar cells Photovoltaic cells Low band gap polymers |
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