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High-pressure defect phase NdxCu3V4O12
Authors:N. I. Kadyrova  Yu. G. Zainulin  V. L. Volkov  G. S. Zakharova  A. V. Korolev
Affiliation:1.Institute of Solid-State Chemistry, Ural Division,Russian Academy of Sciences,Yekaterinburg,Russia;2.Russian Academy of Sciences,Yekaterinburg,Russia
Abstract:A perovskite-like oxide Nd x Cu3V4O12 (space group Im (bar 3) Z = 2, a = 7.278–7.322 Å) with cationic vacancies was prepared for the first time under triaxial compression of p = 6.0–9.0 GPa at 700–1300°C. The compound has a metal-type conductivity, paramagnetic properties, and a phase transition.
Keywords:
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