Controlled synthesis and luminescent properties of Eu(Eu), Dy-doped Sr3Al2O6 phosphors by hydrothermal treatment and postannealing approach |
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Authors: | Xiang Ying Chen Shi Ping Bao |
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Institution: | a School of Chemical Engineering, Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, Hefei University of Technology, Hefei, Anhui 230009, P.R. China b School of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui 230009, P.R. China |
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Abstract: | In this work, Sr3Al2O6: Eu2+ (Eu3+), Dy3+ phosphors have been prepared by hydrothermal treatment and subsequently postannealing approach, using Sr(NO3)2, Al(NO3)3·9H2O, and CO(NH2)2 as starting materials. The as-obtained phosphors were characterized by means of XRPD, FESEM, and PL techniques. In addition, many reaction parameters were studied in detail, including the initial mole ratios, hydrothermal reaction temperature, calcination temperature and calcination atmosphere. Remarkably, two scientific merits exist herein: Sr3Al2O6: Eu2+ (Eu3+), Dy3+ phosphors can be selectively obtained in a reducing atmosphere (H2/Ar, 20%+80%) and in air, respectively; adding certain amount of sodium citrate can alter the shape and size of Sr3Al2O6: Eu2+ (Eu3+), Dy3+ phosphors in essence. Besides, the luminescent properties of Sr3Al2O6: Eu2+ (Eu3+), Dy3+ phosphors were studied by excitation spectra, emission spectra and decay curves. |
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Keywords: | Sr3Al2O6 Phosphor Hydrothermal Postannealing |
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