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Preparation and up-conversion fluorescence of rare earth (Er or Yb/Er)-doped TiO2 nanobelts
Authors:Tianhao Ji  Yang Liu  Haiyan Du  Guanglu Ge
Institution:a College of Chemical and Environmental Engineering, Beijing Technology and Business University, 11 Fucheng Road, Beijing 100048, China
b National Center for Nanoscience and Technology, Beijing 100190, China
Abstract:Anatase TiO2 nanobelts doped with rare earth (RE) ions Yb3+, Er3+ or Yb3+/Er3+ have been prepared using layered titanate nanobelts (LTO NBs) with RE ions as the precursor obtained by ion-exchange between LTO NBs and RE ions under hydrothermal process. Various measurement results demonstrate that the RE ions have doped into the lattice of TiO2, and the Er3+ or Yb3+/Er3+ doped nanobelts show strong visible up-conversion (UC) fluorescence under 980 nm excitation. The UC emission intensity of LTO NBs embedded with Er3+ or Yb3+/Er3+ is slightly higher than that of the corresponding TiO2 nanobelts doped with RE ions, whereas higher RE doping content leads to the decrease of UC emission intensity due to the concentration-quenching effect.
Keywords:TiO2 nanobelts  Rare earth doping  Hydrothermal  Up-conversion
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